Nonlocal Interactions in the Double Perovskite Sr<sub>2</sub>FeMoO<sub>6</sub> from Core-Level X-ray Spectroscopy
نویسندگان
چکیده
The valence electronic structure of the half-metallic double perovskite Sr2FeMoO6 forms from a strongly hybridized band in spin-down channel Fe 3d and Mo 4d states that provides metallic conductivity gapped spin-up channel. ground-state description has previously been explored terms many-body interactions where local nonlocal produce with combination charge-transfer configuration intersite charge fluctuations. Here, we provide qualitative understanding on effects using core-level X-ray spectroscopies, specifically absorption, emission, photoelectron spectroscopies. Our spectroscopic data indicate 4p–O 2p–Mo to be origin these nonlocalized transitions. Close Fermi level, this interaction is dominated by 4d–O 2p character. When our are compared against first-principles calculations, conclude full nature requires spin-resolved hybridization functions screening occurs predominantly through minority spin bands.
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ژورنال
عنوان ژورنال: Journal of Physical Chemistry C
سال: 2021
ISSN: ['1932-7455', '1932-7447']
DOI: https://doi.org/10.1021/acs.jpcc.1c02580